Speciative determination of total V and dissolved inorganic vanadium species in environmental waters by catalytic–kinetic spectrophotometric method
نویسندگان
چکیده
منابع مشابه
Simultaneous Spectrophotometric Determination of Vanadium(V) and Iron(III) in Micellar Medium by H-Point Standard Addition Method
H-Point Standard Addition Method (HPSAM) was applied for the simultaneous determination of V(V) and Fe(III). The method is based on the complex formation of V(V) and Fe(III) with chromazurol S (CAS) in acidic media and in the presence of cetyltrimethylammonium bromide (CTAB) as a micellizing agent. Acidic media and the presence of a micellar system improve selectivity and sensitivity. Fe (I...
متن کاملSpeciative Determination of Dissolved Inorganic Fe(II), Fe(III) and Total Fe in Natural Waters by Coupling Cloud Point Extraction with FAAS
Received 03 May 2013, Revised 28 December 2013, Accepted 31 December 2013 -------------------------------------------------------------------------------------------------------------------------------------------Abstract A new cloud point extraction (CPE) method for the preconcentration of trace iron speciation in natural waters prior to determination by flame atomic absorption spectrometry (F...
متن کاملsimultaneous spectrophotometric determination of vanadium(v) and iron(iii) in micellar medium by h-point standard addition method
h-point standard addition method (hpsam) was applied for the simultaneous determination of v(v) and fe(iii). the method is based on the complex formation of v(v) and fe(iii) with chromazurol s (cas) in acidic media and in the presence of cetyltrimethylammonium bromide (ctab) as a micellizing agent. acidic media and the presence of a micellar system improve selectivity and sensitivity. fe (iii) ...
متن کاملSpectrophotometric method for determination of vanadium and its application to environmental and biological samples
The very sensitive, fairly selective direct spectrophotometric method for the determination of trace amount of vanadium (V) with naphthalene -1, 5 -diamine has been developed. Naphthalene -1, 5 -diamine reacts in slightly acidic (0.0001– 0.001 M H2SO4 or pH 4.0–5.5) alcohol media with vanadium (V) to give a red–violet chelate which has an absorption maximum at 531 nm. The stoichiometric composi...
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تشکیل کمپلکس های tarبا یون های لانتانیم, ایتریم و توریم در دمای 25 درجه، قدرت یونی ثابت 0.1 مولار و در ph ثابت در مخلوط حلال های اتانول – آب و استونیتریل – آب با استفاده از روش های اسپکتروفوتومتری مورد بحث و بررسی قرار گرفت. داده های اسپکتروفوتومتری با استفاده از نرم افزار squad پردازش شدند تا ثابت های تشکیل کمپلکس اندیکاتور – فلز را محاسبه کند. نتایج نشان می دهد که درصد حلال آلی در مخلوط حلال ...
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ژورنال
عنوان ژورنال: Arabian Journal of Chemistry
سال: 2017
ISSN: 1878-5352
DOI: 10.1016/j.arabjc.2012.06.006